MSDS for Turpentine Oil

Identification

Product Name: Turpentine Oil
Chemical Name: Turpentine
Synonyms: Gum Turpentine, Oil of Turpentine
CAS Number: 8006-64-2
Recommended Uses: Paint thinner, solvent for varnishes, cleaning agent, raw material for producing camphor and other chemicals
Supplier Details: Manufacturer or importer’s information must be on the label provided with shipment
Emergency Contact: Poison control center or emergency services listed in local regulation

Hazard Identification

Classification: Flammable liquid, acute toxicity - oral, acute toxicity - inhalation, skin and eye irritant, aspiration hazard
Hazard Statements: Causes skin irritation and severe eye irritation, toxic if inhaled, may cause drowsiness and dizziness, harmful if swallowed, may be fatal if swallowed and enters airways, highly flammable liquid and vapor
Pictograms: Flame, exclamation mark, health hazard, skull and crossbones
Precautionary Statements: Keep away from heat and flames, wear protective gloves and eyewear, avoid breathing vapors, store in a well-ventilated place, wash thoroughly after handling

Composition / Information on Ingredients

Main Ingredient: Turpentine, 100%
CAS Number: 8006-64-2
Chemical Formula: C10H16
Impurities: May contain small amounts of various terpenes, resin acids, and water depending on processing source
Relevant Concentrations: Pure product used in most cases, always check supply certificate for batch-specific details

First Aid Measures

Inhalation: Move victim to fresh air immediately, keep at rest in comfortable position for breathing, call poison control or seek emergency medical help if breathing becomes difficult or symptoms develop
Skin Contact: Take off contaminated clothing, rinse skin with water using plenty of soap, seek medical attention if irritation persists
Eye Contact: Gently flush with water for at least 15 minutes, remove contact lenses if present and easy to do, continue rinsing and seek medical evaluation
Ingestion: Do not induce vomiting, immediately seek medical attention or contact poison control; aspiration into lungs during vomiting can cause severe injury
Most Important Symptoms/Effects: Headache, nausea, dizziness, respiratory distress, chemical burns, pulmonary effects from aspiration

Fire-Fighting Measures

Extinguishing Media: Use foam, dry chemical, or carbon dioxide; do not use water jet as it may spread fire
Specific Hazards: Vapor is heavier than air and may travel along surfaces to distant ignition sources, hazardous decomposition products include carbon monoxide, carbon dioxide, and various irritating smoke compounds
Special Protective Equipment: Firefighters should wear full protective clothing and self-contained breathing apparatus, avoid inhalation of smoke and fumes
Advice for Firefighters: Stay upwind, cool exposed containers with water spray, remove containers from fire area if safe to do so

Accidental Release Measures

Personal Precautions: Evacuate area, eliminate all ignition sources, ventilate spill area, wear protective gloves, eye protection, and suitable respirator
Environmental Precautions: Prevent entry to waterways, drains, and sewers, notify local authorities if product enters environment
Cleanup Procedures: Use inert absorbent material like sand or earth to soak up spillage, collect for disposal using spark-proof tools, wash area with water after complete cleanup

Handling and Storage

Safe Handling Practices: Avoid breathing vapors and contact with skin or eyes, do not eat, drink, or smoke while handling, use spark-free tools and explosion-proof equipment, ground containers when transferring material
Storage Requirements: Store in tightly closed containers in a cool, dry, and well-ventilated area away from heat, sparks, open flames, and incompatible materials like oxidizers or acids, keep containers clearly labeled, avoid excessive storage times, check regularly for leaks or damage

Exposure Controls and Personal Protection

Occupational Exposure Limits: OSHA TWA: 100 ppm (560 mg/m³); ACGIH TLV: 20 ppm
Engineering Controls: Use local exhaust ventilation to keep vapor concentrations below allowable limits, provide emergency eyewash stations and showers
Personal Protection: Wear chemical-resistant gloves, safety goggles, and flame-resistant protective clothing; if ventilation is inadequate or exposure exceeds limits, use approved respirator with organic vapor cartridge
Hygiene Measures: Wash hands and face after handling, remove contaminated clothing before entering eating areas, launder clothing before reuse

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Strong, characteristic pine odor
Odor Threshold: 0.4 ppm (varies by individual sensitivity)
pH: Not applicable
Melting Point/Freezing Point: -55°C
Boiling Point: 154-170°C
Flash Point: 32°C (closed cup)
Evaporation Rate: Moderate, slower than acetone
Flammability: Flammable
Upper/Lower Flammability or Explosive Limits: Upper: 6%, Lower: 0.8% (by volume in air)
Vapor Pressure: 2.8 mmHg @ 20°C
Vapor Density: 4.6 (air=1)
Relative Density: 0.860-0.870
Solubility: Insoluble in water, miscible in organic solvents
Partition Coefficient (n-octanol/water): Not available
Auto-Ignition Temperature: 220°C
Decomposition Temperature: Not determined
Viscosity: Low

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactive Hazards: Reacts vigorously with strong oxidizers, acids, and alkalis; may attack some plastics and rubber materials
Hazardous Decomposition: Carbon monoxide, carbon dioxide, and irritating fumes
Polymerization: Does not form dangerous polymerization products under normal usage

Toxicological Information

Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Toxicity: LD50 (oral, rat) 5760 mg/kg; LC50 (inhalation, rat, 4h) ~13 g/m³
Chronic Effects: Prolonged exposure can cause dermatitis, damage to respiratory system, and kidney or liver damage
Symptoms: Irritation of skin, nose, throat, and eyes, headaches, nausea, drowsiness, fatigue, vomiting, ataxia, confusion; aspiration may cause serious lung injury
Sensitization: Can cause allergic reaction and skin sensitization in susceptible individuals
Carcinogenicity: Not classified as a carcinogen by IARC, ACGIH, NTP, or OSHA
Other Risks: Repeated or prolonged exposure increases risk of adverse health effects, particularly for workers without proper protective practices

Ecological Information

Aquatic Toxicity: Harmful to aquatic life with long lasting effects; toxic to fish and aquatic invertebrates
Persistence and Degradability: Partially biodegradable in environment; breakdown products may also be hazardous
Bioaccumulative Potential: Can accumulate in aquatic organisms
Mobility in Soil: Low water solubility and high volatility favor vapor phase transport
Other Ecological Effects: Spillages can taint surface waters and disrupt local habitats, avoid uncontrolled release into the environment

Disposal Considerations

Waste Treatment Methods: Collect waste in suitable containers and label for hazardous waste disposal, incinerate in approved facility or contract with licensed hazardous waste handler
Disposal of Containers: Triple rinse empty containers, puncture to prevent reuse, deliver to chemical recycling program if available
Precautions: Never pour down drain or into waterways, comply with local, state, federal regulations for hazardous chemical disposal

Transport Information

UN Number: UN 1299
UN Proper Shipping Name: Turpentine
Transport Hazard Classes: 3 (Flammable liquid)
Packing Group: III
Environmental Hazards: Marine pollutant—yes (marine and aquatic life)
Special Precautions: Do not transport with foodstuffs or consumer goods, secure loads, use approved containers for flammable liquids

Regulatory Information

US Regulation: Subject to SARA Title III Section 311/312 hazard categories (acute, fire hazard); TSCA inventory listing; ingredients listed on OSHA hazard communication standard
EU Regulation: Classified as dangerous substance under CLP Regulation (1272/2008); REACH registered
Other Countries: Covered under local chemical safety and environmental legislation—check local requirements
Product Labeling: Requires warning labels for flammable liquid, health hazard, and environmental risk; keep safety data sheet accessible to all users
Worker Training: Staff must receive documented safety training for correct handling, emergency measures, and proper disposal